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Conte, D.E.; Aboulaich, A.; Robert, F.; Olivier-Fourcade, J.; Jumas, J.C.; Jordy, C.; Willmann, P. |
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Title |
Sn-x[BPO4](1-x) composites as negative electrodes for lithium ion cells: Comparison with amorphous SnB0.6P0.4O2.9 and effect of composition |
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Journal Article |
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Year |
2010 |
Publication |
Journal of Solid State Chemistry |
Abbreviated Journal |
J. Solid State Chem. |
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Volume  |
183 |
Issue |
1 |
Pages |
65-75 |
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Keywords |
Sn-based composites; Lithium-ion batteries; Negative electrodes; Mossbauer spectroscopy; LixSn alloys |
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Abstract |
A comparative study of two Sn-based composite materials as negative electrode for Li-ion accumulators is presented. The former SnB0.6P0.4O2.9 obtained by in-situ dispersion of SnO in an oxide matrix is shown to be an amorphous tin composite oxide (ATCO). The latter Sn-0.72[BPO4](0.28) obtained by ex-situ dispersion of Sri in a borophosphate matrix consists of Sri particles embedded in a crystalline BPO4 matrix. The electrochemical responses of ATCO and Sn-0.72.[BPO4](0.28) composite in galvanostatic mode show reversible capacities of about 450 and 530 mAhg(-1), respectively, with different irreversible capacities (60% and 29%). Analysis of these composite materials by Sn-119 Mossbauer spectroscopy in transmission (TMS) and emission (CEMS) modes confirms that ATCO is an amorphous Sn-II composite oxide and shows that in the case of Sn-0.72[BPO4](0.28), the Surface of the tin clusters is mainly formed by Sn-II in an amorphous interface whereas the bulk of the clusters is mainly formed by Sn-0. The determination of the recoilless free fractions f (Lamb-Mossbauer factors) leads to the effective fraction of both Sn-0 and Sn-II species in such composites. The influence of chemical composition and especially of the surface-to-bulk tin species ratio oil the electrochemical behaviour has been analysed for several Sn-x[BPO4](1-x) composite materials (0.17 < x < 0.91). The cell using the compound Sn-0.72[BPO4](0.28) as active material exhibits interesting electrochemical performances (reversible capacity of 500 mAh g(-1) at C/5 rate). (C) 2009 Elsevier Inc. All rights reserved. |
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[Conte, Donato Ercole; Aboulaich, Abdelmaula; Robert, Florent; Olivier-Fourcade, Josette; Jumas, Jean-Claude] Univ Montpellier 2, CNRS, UMR 5253,Inst Charles Gerhardt, Equipe Agregats Interfaces & Mat Energie, F-34095 Montpellier, France, Email: iguanasornione@libero.it |
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ACADEMIC PRESS INC ELSEVIER SCIENCE |
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0022-4596 |
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ISI:000273834600010 |
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EcoFoG @ eric.marcon @ |
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83 |
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Author |
Leroy, C.; Corbara, B.; Dejean, A.; Cereghino, R. |
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Title |
Ants mediate foliar structure and nitrogen acquisition in a tank-bromeliad |
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Journal Article |
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Year |
2009 |
Publication |
New Phytologist |
Abbreviated Journal |
New Phytol. |
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Volume |
183 |
Issue |
4 |
Pages |
1124-1133 |
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Keywords |
Aechmea mertensii; antgardens; Camponotus femoratus; foliar structure; delta N-15; Pachycondyla goeldii; phytotelmata contents |
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Aechmea mertensii is a tank-bromeliad that roots on ant-gardens initiated by the ants Camponotus femoratus and Pachycondyla goeldii. Its leaves form compartments acting as phytotelmata that hold rainwater and provide habitats for invertebrates. In this article, we aimed to determine whether the association with either C. femoratus or P. goeldii influenced the vegetative traits of A. mertensii, invertebrate diversity and nutrient assimilation by the leaves. Transmitted light, vegetative traits and phytotelmata contents were compared between the two A. mertensii ant-gardens. Camponotus femoratus colonized partially shaded areas, whereas P. goeldii colonized exposed areas. The bromeliads' rosettes had a large canopy (C. femoratus ant-gardens), or were smaller and amphora shaped (P. goeldii ant-gardens). There were significant differences in leaf anatomy, as shaded leaves were thicker than exposed leaves. The mean volumes of water, fine particulate organic matter and detritus in C. femoratus-associated bromeliads were three to five times higher than in P. goeldii-associated bromeliads. Moreover, the highest invertebrate diversity and leaf delta N-15 values were found in C. femoratus-associated bromeliads. This study enhances our understanding of the dynamics of biodiversity, and shows how ant-plant interactions can have trophic consequences and thus influence the architecture of the interacting plant via a complex feedback loop. |
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[Leroy, Celine; Dejean, Alain] EcoFoG, CNRS, UMR 8172, F-97379 Kourou, France, Email: Celine.Leroy@ecofog.gf |
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WILEY-BLACKWELL PUBLISHING, INC |
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0028-646X |
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ISI:000268855300020 |
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EcoFoG @ eric.marcon @ |
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106 |
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Author |
Salas-Lopez, A.; Mickal, H.; Menzel, F.; Orivel, J. |
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Title |
Ant-mediated ecosystem processes are driven by trophic community structure but mainly by the environment |
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Journal Article |
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Year |
2017 |
Publication |
Oecologia |
Abbreviated Journal |
Oecologia |
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Volume |
183 |
Issue |
1 |
Pages |
249-261 |
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The diversity and functional identity of organisms are known to be relevant to the maintenance of ecosystem processes but can be variable in different environments. Particularly, it is uncertain whether ecosystem processes are driven by complementary effects or by dominant groups of species. We investigated how community structure (i.e., the diversity and relative abundance of biological entities) explains the community-level contribution of Neotropical ant communities to different ecosystem processes in different environments. Ants were attracted with food resources representing six ant-mediated ecosystem processes in four environments: ground and vegetation strata in cropland and forest habitats. The exploitation frequencies of the baits were used to calculate the taxonomic and trophic structures of ant communities and their contribution to ecosystem processes considered individually or in combination (i.e., multifunctionality). We then investigated whether community structure variables could predict ecosystem processes and whether such relationships were affected by the environment. We found that forests presented a greater biodiversity and trophic complementarity and lower dominance than croplands, but this did not affect ecosystem processes. In contrast, trophic complementarity was greater on the ground than on vegetation and was followed by greater resource exploitation levels. Although ant participation in ecosystem processes can be predicted by means of trophic-based indices, we found that variations in community structure and performance in ecosystem processes were best explained by environment. We conclude that determining the extent to which the dominance and complementarity of communities affect ecosystem processes in different environments requires a better understanding of resource availability to different species. |
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1432-1939 |
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EcoFoG @ webmaster @ Salas-Lopez2017 |
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715 |
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Medjigbodo, G.; Rozière, E.; Charrier, K.; Izoret, L.; Loukili, A. |
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Title |
Hydration, shrinkage, and durability of ternary binders containing Portland cement, limestone filler and metakaolin |
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Journal Article |
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2018 |
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Construction and Building Materials |
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183 |
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114-126 |
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Durability; Limestone filler; Metakaolin; Shrinkage; Strength; Ternary binders |
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A partial replacement of the clinker by latent hydraulic or pozzolanic materials is encouraged due to environmental and specific technical requirements. Such substitution remains limited to a relatively low level (less than 30% by mass of cementitious materials). An experimental research work was carried out on mortars made with binary and ternary binders (Portland cement; metakaolin; limestone filler) to reach 45% total replacement. In order to investigate the activating effect of reduced water-to-cement ratio, two series of mixtures were designed with W/C0 of 0.42 and 0.5. Their heat of hydration, portlandite content, shrinkage, porosity, and carbonation were monitored. The tests were performed to understand the evolution of their relative strength (activity index) and durability parameters. The strength development of mortars with ternary binders was found to depend on metakaolin properties, including manufacturing process and particle size distribution. Reducing W/C0 ratio accelerated pozzolanic reaction and allowed improving early-age strength and durability parameters. © 2018 Elsevier Ltd |
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Association Technique de l'Industrie des Liants Hydrauliques (ATILH), 7 place de la Défense, Paris La Défense, 92974, France |
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Export Date: 1 September 2018 |
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EcoFoG @ webmaster @ |
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814 |
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Ghislain, B.; Nicolini, E.-A.; Romain, R.; Ruelle, J.; Yoshinaga, A.; Alford, M.H.; Clair, B. |
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Title |
Multilayered structure of tension wood cell walls in Salicaceae sensu lato and its taxonomic significance |
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Journal Article |
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2016 |
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Botanical Journal of the Linnean Society |
Abbreviated Journal |
Bot. J. Linn. Soc. |
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182 |
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4 |
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744-756 |
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Flacourtiaceae; G-layer; multilayered tension wood; reaction wood |
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Salicaceae have been enlarged to include a majority of the species formerly placed in the polyphyletic tropical Flacourtiaceae. Several studies have reported a peculiar and infrequently formed multilayered structure of tension wood in four of the tropical genera. Tension wood is a tissue produced by trees to restore their vertical orientation and most studies have focused on trees developing tension wood by means of cellulose-rich, gelatinous fibres, as in Populus and Salix (Salicaceae s.s.). This study aims to determine if the multilayered structure of tension wood is an anatomical characteristic common in other Salicaceae and, if so, how its distribution correlates to phylogenetic relationships. Therefore, we studied the tension wood of 14 genera of Salicaceae and two genera of Achariaceae, one genus of Goupiaceae and one genus of Lacistemataceae, families closely related to Salicaceae or formerly placed in Flacourtiaceae. Opposite wood and tension wood were compared with light microscopy and three-dimensional laser scanning confocal microscopy. The results indicate that a multilayered structure of tension wood is common in the family except in Salix, Populus and one of their closest relatives, Idesia polycarpa. We suggest that tension wood may be a useful anatomical character in understanding phylogenetic relationships in Salicaceae. Further investigation is still needed on the tension wood of several other putatively close relatives of Salix and Populus, in particular Bennettiodendron, Macrohasseltia and Itoa. |
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1095-8339 |
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EcoFoG @ webmaster @ |
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718 |
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Author |
Vedel, V.; Scotti, I. |
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Title |
Promoting the promoter |
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Journal Article |
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Year |
2011 |
Publication |
Plant Science |
Abbreviated Journal |
Plant Sci. |
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180 |
Issue |
2 |
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182-189 |
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Keywords |
cis-Regulation; Evolutionary and developmental biology; Integrative evolution; Plant development; Population genetics; Transcription |
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Recent evolutionary studies clearly indicate that evolution is mainly driven by changes in the complex mechanisms of gene regulation and not solely by polymorphism in protein-encoding genes themselves. After a short description of the cis-regulatory mechanism, we intend in this review to argue that by applying newly available technologies and by merging research areas such as evolutionary and developmental biology, population genetics, ecology and molecular cell biology it is now possible to study evolution in an integrative way. We contend that, by analysing the effects of promoter sequence variation on phenotypic diversity in natural populations, we will soon be able to break the barrier between the study of extant genetic variability and the study of major developmental changes. This will lead to an integrative view of evolution at different scales. Because of their sessile nature and their continuous development, plants must permanently regulate their gene expression to react to their environment, and can, therefore, be considered as a remarkable model for these types of studies. (C) 2010 Elsevier Ireland Ltd. All rights reserved. |
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[Vedel, Vincent; Scotti, Ivan] INRA, UMR ECOFOG, Kourou 97387, French Guiana, Email: vincent.vedel@ecofog.gf |
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ELSEVIER IRELAND LTD |
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0168-9452 |
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ISI:000286562200002 |
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no |
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EcoFoG @ eric.marcon @ |
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291 |
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Phillips, P.D.; Thompson, I.S.; Silva, J.N.M.; van Gardingen, P.R.; Degen, B. |
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Title |
Scaling up models of tree competition for tropical forest population genetics simulation |
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Journal Article |
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Year |
2004 |
Publication |
Ecological Modelling |
Abbreviated Journal |
Ecol. Model. |
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180 |
Issue |
2-3 |
Pages |
419-434 |
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Keywords |
tropical rain; forest; population genetics; model SYMFOR; eco-gene; scaling up; competition |
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Understanding the effects of logging activity on genetic diversity is an important aspect of establishing the sustainability of selective logging management operations in tropical forests. Genetic variation is affected by selective logging directly, through the removal of and damage to trees within the population, and indirectly, through a change in the forest structure and environment in which the remaining population lives. Eco-Gene is a population genetics model applied to tropical forests over a scale of hundreds of hectares. SYMFOR is a modelling framework for individual-based spatially explicit ecological and management models applied to tropical forests over a scale of 0.25 4 ha. We have linked the models to enable simulations using processes involved in both models. To overcome problems of scale, the spatially explicit competition index calculated in SYMFOR simulations has been modelled such that it can be applied at scales representing much larger areas for which the data are not available, as required by Eco-Gene. The competition index is modelled as a distribution on a grid-square basis, and implemented in the linked Eco-Gene/SYMFOR system. Each tree within a grid-square is given a “relative competition” within the distribution, biased according to species. A competition index value is obtained for the tree by transforming the grid-square distribution to be relevant to the size of the tree, and extracting a value according to the tree's relative competition within the distribution. The distribution and each tree's relative competition within it change according to the effects of growth, mortality and logging activity. The model was calibrated using data from the Tapajos region of the Eastern Amazon forest. This paper describes the model, its calibration and validation and the implications of scaling up from an explicit representation to a modelled quantity. (C) 2004 Elsevier B.V. All rights reserved. |
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Address |
Embrapa Amazonia Oriental, BR-66095100 Belem, Para, Brazil, Email: paul.phillips@envams.co.uk |
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ELSEVIER SCIENCE BV |
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0304-3800 |
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ISI:000224635700012 |
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EcoFoG @ eric.marcon @ |
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234 |
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Hattenschwiler, S.; Aeschlimann, B.; Couteaux, M.M.; Roy, J.; Bonal, D. |
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Title |
High variation in foliage and leaf litter chemistry among 45 tree species of a neotropical rainforest community |
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Journal Article |
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Year |
2008 |
Publication |
New Phytologist |
Abbreviated Journal |
New Phytol. |
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179 |
Issue |
1 |
Pages |
165-175 |
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Keywords |
French Guiana; interspecific and intraspecific variation; leaf litter traits; neotropical rainforest; nitrogen; nutrient resorption; phosphorus; stoichiometry |
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Distinct ecosystem level carbon : nitrogen : phosphorus (C : N : P) stoichiometries in forest foliage have been suggested to reflect ecosystem-scale selection for physiological strategies in plant nutrient use. Here, this hypothesis was explored in a nutrient-poor lowland rainforest in French Guiana. Variation in C, N and P concentrations was evaluated in leaf litter and foliage from neighbour trees of 45 different species, and the litter concentrations of major C fractions were also measured. Litter C ranged from 45.3 to 52.4%, litter N varied threefold (0.68-2.01%), and litter P varied seven-fold (0.009-0.062%) among species. Compared with foliage, mean litter N and P concentrations decreased by 30% and 65%, respectively. Accordingly, the range in mass-based N : P shifted from 14 to 55 in foliage to 26 to 105 in litter. Resorption proficiencies indicated maximum P withdrawal in most species, but with a substantial increase in variation in litter P compared with foliage. These data suggest that constrained ecosystem-level C : N : P ratios do not preclude the evolution of highly diversified strategies of nutrient use and conservation among tropical rainforest tree species. The resulting large variation in litter quality will influence stoichiometric constraints within the decomposer food web, with potentially far-ranging consequences on nutrient dynamics and plant-soil feedbacks. |
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[Haettenschwiler, Stephan; Aeschlimann, Beat; Couteaux, Marie-Madeleine; Roy, Jacques] CEFE, CNRS, F-34293 Montpellier 5, France, Email: stephan.hattenschwiler@cefe.cnrs.fr |
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BLACKWELL PUBLISHING |
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0028-646X |
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ISI:000256412500017 |
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EcoFoG @ eric.marcon @ |
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139 |
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Sist, P.; Sheil, D.; Kartawinata, K.; Priyadi, H. |
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Title |
Reduced-impact logging in Indonesian Borneo: some results confirming the need for new silvicultural prescriptions |
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Journal Article |
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2003 |
Publication |
Forest Ecology and Management |
Abbreviated Journal |
For. Ecol. Manage. |
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179 |
Issue |
1-3 |
Pages |
415-427 |
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Abstract |
Reduced-impact logging (RIL) and conventional techniques (CNV) were compared in a mixed dipterocarp hill forest in East Kalimantan in three blocks of about 100 ha each. Damage was evaluated using pre- and post-harvesting assessments in 24 one-hectare sample plots. RIL techniques nearly halved the number of trees destroyed (36 vs 60 trees/ha). RIL's main benefit was in the reduction of skidding damage (9.5% of the original tree population in RIL vs 25% in CNV). Before logging, mean canopy openness in CNV (three plots only) and RIL (9 plots) was similar (3.6 and 3.1%) and not significantly different (x(2) = 2.73, P = 0.254). After logging, the mean canopy openness was 19.2% in CNV (n = 9 plots) and 13.3% in RIL (n = 8 plots), and the distributions of the canopy class in RIL and CNV significantly different x(2) = 43.56, P < 0.001). CNV plots showed a higher proportion of measurements in the most open class greater than or equal to30% than in RIL. At a larger scale, the area of skidtrail per unit timber volume extracted was halved in the RIL compartment (15 m(2) vs 27 m(2) m(-3) for CNV). However, under high felling intensity (>8 trees/ha), both stand damage and canopy disturbance in RIL approached those recorded in CNV under low or moderate felling regime. Over this felling intensity threshold the effectiveness of RIL in reducing tree damage is limited. In mixed dipterocarp forest where harvestable timber density generally exceeds 10 trees/ha, a minimum diameter felling limit is clearly insufficient to keep extraction rates below 8 trees/ha. Based on these new results and previous studies in Borneo, we suggest three silvicultural rules: (1) to keep a minimum distance between stumps of ca. 40 m, (2) to ensure only single tree gaps using directional felling, (3) to harvest only stems with 60-100 cm dbh. Foresters, policy makers and certifiers should consider these as criteria for sustainable forest management. We emphasise the need to expand harvesting studies to look at impacts and trade-offs across larger forest landscapes, to expand RIL beyond silvicultural concepts and to include the maintenance of other forest goods and services. (C) 2002 Elsevier Science B.V. All rights reserved. |
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0378-1127 |
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WOS:000183836300033 |
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EcoFoG @ webmaster @ |
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311 |
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Sardans, J.; Urbina, I.; Grau, O.; Asensio, D.; Ogaya, R.; Peñuelas, J. |
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Title |
Long-term drought decreases ecosystem C and nutrient storage in a Mediterranean holm oak forest |
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Journal Article |
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2020 |
Publication |
Environmental and Experimental Botany |
Abbreviated Journal |
Environ. Exp. Bot. |
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Volume |
177 |
Issue |
104135 |
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Aridity; Carbon stocks; Climate change; Nitrogen; Phosphorus; Potassium; Stoichiometry; carbon sequestration; deciduous forest; drought; experimental study; forest soil; long-term change; Mediterranean environment; net ecosystem exchange; nutrient cycling; shrub; stoichiometry; Mediterranean Sea; Phillyrea latifolia |
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Abstract |
Aridity has increased in recent decades in the Mediterranean Basin and is projected to continue to increase in the coming decades. We studied the consequences of drought on the concentrations, stoichiometries and stocks of carbon (C), nitrogen (N), phosphorus (P) and potassium (K) in leaves, foliar litter of a three dominant woody species and soil of a Mediterranean montane holm oak forest where soil-water content was experimentally reduced (15 % lower than the control plots) for 15 years. Nitrogen stocks were lower in the drought plots than in the control plots (8.81 ± 1.01 kg ha−1 in the forest canopy and 856 ± 120 kg ha−1 in the 0−15 cm soil layer), thus representing 7 and 18 % lower N stocks in the canopy and soil respectively. δ15N was consistently higher under drought conditions in all samples, indicating a general loss of N. Foliar C and K stocks were also lower but to a lesser extent than N. Decreases in biomass and C and N stocks due to drought were smallest for the most dominant tall shrub, Phillyrea latifolia, so our results suggest a lower capacity of this forest to store C and nutrients but also substantial resulting changes in forest structure with increasing drought. © 2020 Elsevier B.V. |
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Cirad, UMR EcoFoG (AgroParisTech, CNRS, Inra, Univ Antilles, Univ Guyane), Campus Agronomique, Kourou, 97310, French Guiana |
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Elsevier B.V. |
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00988472 (Issn) |
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EcoFoG @ webmaster @ |
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954 |
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