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Author Lebrini, M.; Mbomekallé, I.M.; Dolbecq, A.; Marrot, J.; Berthet, P.; Ntienoue, J.; Sécheresse, F.; Vigneron, J.; Etcheberry, A. url  openurl
  Title Manganese(III)-containing wells-dawson sandwich-type polyoxometalates: Comparison with their manganese(II) counterparts Type Journal Article
  Year (up) 2011 Publication Inorganic Chemistry Abbreviated Journal Inorg. Chem.  
  Volume 50 Issue 14 Pages 6437-6448  
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  Abstract We present the synthesis and structural characterization, assessed by various techniques (FTIR, TGA, UV-vis, elemental analysis, single-crystal X-ray diffraction for three compounds, magnetic susceptibility, and electrochemistry) of five manganese-containing Wells-Dawson sandwich-type (WDST) complexes. The dimanganese(II)-containing complex, [Na2(H2O) 2MnII2(As2W15O 56)2]18- (1), was obtained by reaction of MnCl2 with 1 equiv of [As2W15O 56]12- in acetate medium (pH 4.7). Oxidation of 1 by Na2S2O8 in aqueous solution led to the dimanganese(III) complex [Na2(H2O)2Mn III2(As2W15O56) 2]16- (2), while its trimanganese(II) homologue, [Na(H2O)2MnII(H2O)Mn II2(As2W15O56) 2]17- (3), was obtained by addition of ca. 1 equiv of MnCl2 to a solution of 1 in 1 M NaCl. The trimanganese(III) and tetramanganese(III) counterparts, [MnIII(H2O)Mn III2(As2W15O56) 2]15- (4) and [MnIII2(H 2O)2MnIII2(As2W 15O56)2]12- (6), are, respectively, obtained by oxidation of aqueous solutions of 3 and [MnII2(H2O)2MnII2(As 2W15O56)2]16- (5) by Na2S2O8. Single-crystal X-ray analyses were carried out on 2, 3, and 4. BVS calculations and XPS confirmed that the oxidation state of Mn centers is +II for complexes 1, 3, and 5 and +III for 2, 4, and 6. A complete comparative electrochemical study was carried out on the six compounds cited above, and it was possible to observe the distinct redox steps MnIV/III and MnIII/II. Magnetization measurements, as a function of temperature, confirm the presence of antiferromagnetic interactions between the Mn ions in these compounds in all cases with the exception of compound 2. © 2011 American Chemical Society.  
  Address Laboratoire de Physico-Chimie de L'Etat Solide, ICMMO, Université Paris-Sud, Bâtiment 410, 91405 Orsay Cedex, France  
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  ISSN 00201669 (Issn) ISBN Medium  
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  Notes Export Date: 21 October 2011; Source: Scopus; Coden: Inoca; doi: 10.1021/ic102237x; Language of Original Document: English; Correspondence Address: Mbomekallé, I.M.; Institut Lavoisier de Versailles, UMR 8180, CNRS Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France; email: israel.mbomekalle@chimie.uvsq.fr Approved no  
  Call Number EcoFoG @ webmaster @ Serial 346  
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Author Lebrini, M.; Roos, C.; Vezin, H.; Robert, F. pdf  url
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  Title Electrochemical and theoretical studies of adsorption of some indole derivates at C38 Steel/Sulfuric acid interface as corrosion inhibitors Type Journal Article
  Year (up) 2011 Publication International Journal of Electrochemical Science Abbreviated Journal Int.J.Electrochem.Sci.  
  Volume 6 Issue 9 Pages 3844-3857  
  Keywords Acidic media; Adsorption; C38 steel; Corrosion inhibitors; Theoretical calculations  
  Abstract The inhibitive action of 9H-pyrido[3,4-b]indole (norharmane) and 1-Methyl-9H-pyrido[3,4-b]indole (harmane) on corrosion of C38 steel in 0.5 M H2SO4 solution was investigated through electrochemical techniques. The experimental results obtained revealed that these compounds inhibited the steel corrosion in acid solution for all concentrations studied. Polarization measurements indicate that the examined compounds act as a mixed inhibitor and its inhibition efficiency increases with inhibitor concentration. Data obtained from ac impedance technique show a frequency distribution and therefore a modelling element with frequency dispersion behaviour, a constant phase element (CPE), has been used. The adsorption of used compounds on the steel surface obeys Langmuir's isotherm. The ΔG°ads values were calculated and discussed for both inhibitors. Significant correlations are obtained between inhibition efficiency and quantum chemical parameters using quantitative structure-activity relationship (QSAR) method. © 2011 by ESG.  
  Address Laboratoire de Chimie Organique et Macromoléculaire, UMR-CNRS 8009, USTL BâtC4, F-59655 Villeneuve d'Ascq Cedex, France  
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  ISSN 14523981 (Issn) ISBN Medium  
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  Notes Export Date: 21 October 2011; Source: Scopus; Language of Original Document: English; Correspondence Address: Robert, F.; Laboratoire Matériaux et Molécules en Milieu Amazonien, UAG-UMR ECOFOG, Campus Trou Biran, Cayenne 97337, French Guiana; email: florent.robert@guyane.univ-ag.fr Approved no  
  Call Number EcoFoG @ webmaster @ Serial 347  
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Author Faustin, M.; Lebrini, M.; Robert, F.; Roos, C. pdf  url
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  Title Corrosion studies of C38 steel by alkaloids extract of a tropical plant type Type Journal Article
  Year (up) 2011 Publication International Journal of Electrochemical Science Abbreviated Journal Int.J.Electrochem.Sci.  
  Volume 6 Issue 9 Pages 4095-4113  
  Keywords Acidic media; C38 steel; Corrosion inhibitor; Plant extract  
  Abstract Alkaloids extract of Aspidosperma album was tested as corrosion inhibitor for C38 steel in 1 M HCl by using polarization and electrochemical impedance spectroscopy (EIS). Potentiodynamic polarization curves indicated that the plant extract behaves as mixed-type inhibitors. Impedance measurements showed that the double-layer capacitance decreased and charge-transfer resistance increased with increase in the inhibitors concentration and hence increasing in inhibition efficiency. The effect of temperature on the corrosion behavior of C38 steel in 1 M HCl with and without addition of plant extract was studied in the temperature range 25 – 55°C. The adsorption of the inhibitor molecules was in accordance with the Langmuir adsorption isotherm. The results obtained show that this plant extract could serve as an effective inhibitor for the corrosion of C38 steel in hydrochloric acid. © 2011 by ESG.  
  Address Laboratoire Matériaux et Molécules en Milieu Amazonien, UAG-UMR ECOFOG, Campus Trou Biran, Cayenne 97337, French Guiana  
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  ISSN 14523981 (Issn) ISBN Medium  
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  Notes Export Date: 21 October 2011; Source: Scopus; Language of Original Document: English; Correspondence Address: Roos, C.; Laboratoire Matériaux et Molécules en Milieu Amazonien, UAG-UMR ECOFOG, Campus Trou Biran, Cayenne 97337, French Guiana; email: florent.robert@guyane.univ-ag.fr Approved no  
  Call Number EcoFoG @ webmaster @ Serial 348  
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Author Staudt, K.; Serafimovich, A.; Siebicke, L.; Pyles, R.D.; Falge, E. url  openurl
  Title Vertical structure of evapotranspiration at a forest site (a case study) Type Journal Article
  Year (up) 2011 Publication Agricultural and Forest Meteorology Abbreviated Journal Agric. For. Meterol.  
  Volume 151 Issue 6 Pages 709-729  
  Keywords Eddy-covariance; Evapotranspiration; In-canopy profiles; Model; Picea abies L.; Sap flux; coniferous forest; ecosystem modeling; eddy covariance; evapotranspiration; forest canopy; sap flow; Fichtelgebirge; Germany; Picea abies  
  Abstract The components of ecosystem evapotranspiration of a Norway spruce forest (Picea abies L.) as well as the vertical structure of canopy evapotranspiration were analyzed with a combination of measurements and models for a case study of 5 days in September 2007. Eddy-covariance and sap flux measurements were performed at several heights within the canopy at the FLUXNET site Waldstein-Weidenbrunnen (DE-Bay) in the Fichtelgebirge mountains in Germany. Within and above canopy fluxes were simulated with two stand-scale models, the 1D multilayer model ACASA that includes a third-order turbulence closure and the 3D model STANDFLUX. The soil and understory evapotranspiration captured with the eddy-covariance system in the trunk space constituted 10% of ecosystem evapotranspiration measured with the eddy-covariance system above the canopy. A comparison of transpiration measured with the sap flux technique and inferred from below and above canopy eddy-covariance systems revealed higher estimates from eddy-covariance measurements than for sap flux measurements. The relative influences of possible sources of this mismatch, such as the assumption of negligible contribution of evaporation from intercepted water, and differences between the eddy-covariance flux footprint and the area used for scaling sap flux measurements, were discussed. Ecosystem evapotranspiration as well as canopy transpiration simulated with the two models captured the dynamics of the measurements well, but slightly underestimated eddy-covariance values. Profile measurements and models also gave us the chance to assess in-canopy profiles of canopy evapotranspiration and the contributions of in-canopy layers. For daytime and a coupled or partly coupled canopy, mean simulated profiles of both models agreed well with eddy-covariance measurements, with a similar performance of the ACASA and the STANDFLUX model. Both models underestimated profiles for nighttime and decoupled conditions. During daytime, the upper half of the canopy contributed approximately 80% to canopy evapotranspiration, whereas during nighttime the contribution shifted to lower parts of the canopy. © 2010 Elsevier B.V.  
  Address Max Planck Institute for Chemistry, Biogeochemistry Department, Joh.-J.-Becherweg 27, 55128 Mainz, Germany  
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  ISSN 01681923 (Issn) ISBN Medium  
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  Notes Cited By (since 1996): 3; Export Date: 21 October 2011; Source: Scopus; Coden: Afmee; doi: 10.1016/j.agrformet.2010.10.009; Language of Original Document: English; Correspondence Address: Staudt, K.; University of Bayreuth, Department of Micrometeorology, 95440 Bayreuth, Germany; email: katharina.staudt@uni-bayreuth.de Approved no  
  Call Number EcoFoG @ webmaster @ Serial 349  
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Author Rodrigues, A.M.; Amusant, N.; Beauchene, J.; Eparvier, V.; Lemenager, N.; Baudasse, C.; Espindola, L.S.; Stien, D. url  openurl
  Title The termiticidal activity of Sextonia rubra (Mez) van der Werff (Lauraceae) extract and its active constituent rubrynolide Type Journal Article
  Year (up) 2011 Publication Pest Management Science Abbreviated Journal Pest Manage. Sci.  
  Volume 67 Issue 11 Pages 1420-1423  
  Keywords Nasutitermes macrocephalus; Reticulitermes flavipes; Rubrynolide; Sextonia rubra extract; Wood preservation  
  Abstract Termites are degradation agents that inflict severe damage on wood. Some long-lasting Amazonian trees can resist these insects by producing toxic secondary metabolites. These metabolites could potentially replace synthetic termiticidal products which are becoming more restricted to use. Results: Sextonia rubra is resistant to termite-induced degradation. It has been demonstrated that this species naturally produces an ethyl-acetate-soluble termiticidal metabolite, rubrynolide, to protect its wood. Assays in the presence of tropical and invasive termites established that both rubrynolide and crude ethyl acetate extract from S. rubra wood can be used as a treatment for the protection of sensitive woods against termites. Conclusion: Rubrynolide and S. rubra extract are promising candidates for the replacement of synthetic termiticides. © 2011 Society of Chemical Industry.  
  Address CNRS-Institut de Chimie des Substances Naturelles, Gif-sur-Yvette, France  
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  ISSN 1526498x (Issn) ISBN Medium  
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  Notes Export Date: 26 October 2011; Source: Scopus; Coden: Pmscf; doi: 10.1002/ps.2167; Language of Original Document: English; Correspondence Address: Rodrigues, A.M.; UMR Ecofog, Institut d'Enseignement Supérieur de la Guyane, BP792, 97337 Cayenne Cedex, France; email: alice.rodrigues@pop.com.br Approved no  
  Call Number EcoFoG @ webmaster @ Serial 362  
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Author Odonne, G.; Herbette, G.; Eparvier, V.; Bourdy, G.; Rojas, R.; Sauvain, M.; Stien, D. url  openurl
  Title Antileishmanial sesquiterpene lactones from Pseudelephantopus spicatus, a traditional remedy from the Chayahuita Amerindians (Peru). Part III Type Journal Article
  Year (up) 2011 Publication Journal of Ethnopharmacology Abbreviated Journal J. Ethnopharmacol.  
  Volume 137 Issue 1 Pages 875-879  
  Keywords Asteraceae; Chayahuita; Hirsutinolides; Leishmaniasis; Peru; Pseudelephantopus spicatus; Traditional remedy; 8,13 diacetylpiptocarphol; acetyl 13 o ethylpiptocarphol; amphotericin B; antileishmanial agent; plant extract; Pseudelephantopus spicatus extract; sesquiterpene lactone derivative; unclassified drug; ursolic acid; amastigote; article; biological activity; Ic 50; in vitro study; Leishmania; leishmaniasis; medicinal plant; nonhuman; Peru; Pseudelephantopus spicatus; traditional medicine; Asteraceae; Leishmania amazonensis; Pseudelephantopus spicatus  
  Abstract Ethnopharmacological relevance: The study of traditional remedies used by the Chayahuita, an ethnic group from the Peruvian Amazonia, has prompted us to investigate in detail the ethanolic extract of Pseudelephantopus spicatus (Juss. ex Aubl.) C.F. Baker, which has demonstrated strong biological activity towards Leishmania amazonensis. Our goal was to discover the active compound of this plant-based remedy. Materials and methods: A bioguided fractionation of the crude extract was undertaken based on the biological activity recorded against Leishmania amazonensis axenic amastigotes in in vitro bioassays. Results: Three strongly to moderately active compounds were isolated: two hirsutinolides (the 8,13-diacetyl-piptocarphol and the 8-acetyl-13-O-ethyl-piptocarphol) and ursolic acid. IC50 against Leishmania amazonensis axenic amastigotes are respectively 0.2, 0.37 and 0.99 μM (while IC50 of amphotericin B is 0.41 μM). These compounds have never been isolated from this plant species, and germacranolides have never been identified as potential antileishmanial agents. Conclusions: The compounds isolated from Pseudelephantopus spicatus account for the antileishmanial activity of the plant, thus giving support to its use by the Chayahuita in Peru. © 2011 Elsevier Ireland Ltd All rights reserved.  
  Address Laboratorio de Investigación y Desarrollo, Facultad de Ciencias y Filosofía, Universidad Peruana Cayetano Heredia, Avenida Honorio Delgado 430, San Martin de Porres, Lima, Peru  
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  ISSN 03788741 (Issn) ISBN Medium  
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  Notes Export Date: 21 October 2011; Source: Scopus; Coden: Joetd; doi: 10.1016/j.jep.2011.07.008; Language of Original Document: English; Correspondence Address: Odonne, G.; Bureau du CNRS en Guyane, CNRS – UPS 2561, 2 Avenue Gustave Charlery, 97300 Cayenne, France; email: guillaume.odonne@gmail.com; Chemicals/CAS: amphotericin B, 1397-89-3, 30652-87-0; ursolic acid, 77-52-1 Approved no  
  Call Number EcoFoG @ webmaster @ Serial 350  
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Author Gourlet-Fleury, S.; Rossi, V.; Rejou-Mechain, M.; Freycon, V.; Fayolle, A.; Saint-André, L.; Cornu, G.; Gérard, J.; Sarrailh, J.-M.; Flores, O.; Baya, F.; Billand, A.; Fauvet, N.; Gally, M.; Henry, M.; Hubert, D.; Pasquier, A.; Picard, N. url  openurl
  Title Environmental filtering of dense-wooded species controls above-ground biomass stored in African moist forests Type Journal Article
  Year (up) 2011 Publication Journal of Ecology Abbreviated Journal J. Ecol.  
  Volume 99 Issue 4 Pages 981-990  
  Keywords Basal area; Central African Republic; Determinants of plant community diversity and structure; Life-history strategy; Soil fertility; Species sorting; Vital rates; Water reserve; Wood density; aboveground biomass; basal area; climate change; data set; database; diameter; forest ecosystem; forest inventory; life history trait; nutrient availability; physical property; plant community; resource availability; soil fertility; soil nutrient; soil texture; soil type; stem; tropical forest; wood; Central African Republic  
  Abstract 1.Regional above-ground biomass estimates for tropical moist forests remain highly inaccurate mostly because they are based on extrapolations from a few plots scattered across a limited range of soils and other environmental conditions. When such conditions impact biomass, the estimation is biased. The effect of soil types on biomass has especially yielded controversial results. 2.We investigated the relationship between above-ground biomass and soil type in undisturbed moist forests in the Central African Republic. We tested the effects of soil texture, as a surrogate for soil resources availability and physical constraints (soil depth and hydromorphy) on biomass. Forest inventory data were collected for trees ≥20cm stem diameter in 2754 0.5ha plots scattered over 4888km2. The plots contained 224 taxons, of which 209 were identified to species. Soil types were characterized from a 1:1000000 scale soil map. Species-specific values for wood density were extracted from the CIRAD's data base of wood technological properties. 3.We found that basal area and biomass differ in their responses to soil type, ranging from 17.8m2ha-1 (217.5tha-1) to 22.3m2ha-1 (273.3tha-1). While shallow and hydromorphic soils support forests with both low stem basal area and low biomass, forests on deep resource-poor soils are typically low in basal area but as high in biomass as forests on deep resource-rich soils. We demonstrated that the environmental filtering of slow growing dense-wooded species on resource-poor soils compensates for the low basal area, and we discuss whether this filtering effect is due to low fertility or to low water reserve. 4.Synthesis. We showed that soil physical conditions constrained the amount of biomass stored in tropical moist forests. Contrary to previous reports, our results suggest that biomass is similar on resource-poor and resource-rich soils. This finding highlights both the importance of taking into account soil characteristics and species wood density when trying to predict regional patterns of biomass. Our findings have implications for the evaluation of biomass stocks in tropical forests, in the context of the international negotiations on climate change. © 2011 The Authors. Journal of Ecology © 2011 British Ecological Society.  
  Address CIRAD, BP 4035, Libreville, Gabon  
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  ISSN 00220477 (Issn) ISBN Medium  
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  Notes Cited By (since 1996): 1; Export Date: 23 October 2011; Source: Scopus; Coden: Jecoa; doi: 10.1111/j.1365-2745.2011.01829.x; Language of Original Document: English; Correspondence Address: Gourlet-Fleury, S.; Cirad, UR BandSEF, Biens et Services des Ecosystèmes Forestiers tropicaux, Campus International de Baillarguet, TA C-105/D, F-34398, Montpellier, France; email: sylvie.gourlet-fleury@cirad.fr Approved no  
  Call Number EcoFoG @ webmaster @ Serial 361  
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Author Zhang, T.; Bai, S.-L.; Bardet, S.; Almeras, T.; Thibaut, B.; Beauchene, J. url  openurl
  Title Radial variations of vibrational properties of three tropical woods Type Journal Article
  Year (up) 2011 Publication Journal of Wood Science Abbreviated Journal J. Wood Sci.  
  Volume 57 Issue 5 Pages 377-386  
  Keywords Damping coefficient; Dynamic modulus; Extractives; Microfibril angle; Tropical woods  
  Abstract The radial trends of vibrational properties, represented by the specific dynamic modulus (E′/ρ) and damping coefficient (tan δ), were investigated for three tropical rainforest hardwood species (Simarouba amara, Carapa procera, and Symphonia globulifera) using free-free flexural vibration tests. The microfibril angle (MFA) was estimated using X-ray diffraction. Consistent patterns of radial variations were observed for all studied properties. E′/ρ was found to decrease from pith to bark, which was strongly related to the increasing pith-bark trend of MFA. The variation of tan δ along the radius could be partly explained by MFA and partly by the gradient of extractives due to heartwood formation. The coupling effect of MFA and extractives could be separated through analysis of the log(tan δ) versus log(E′/ρ) diagram. For the species studied, the extractive content putatively associated with heartwood formation generally tends to decrease the wood damping coefficient. However, this weakening effect of extractives was not observed for the inner part of the heartwood, suggesting that the mechanical action of extractives was reduced during their chemical ageing. © 2011 The Japan Wood Research Society.  
  Address CIRAD, UMR Ecofog, BP 701, 97387 Kourou Cedex, Guyane Française, France  
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  ISSN 14350211 (Issn) ISBN Medium  
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  Notes Export Date: 26 October 2011; Source: Scopus; Coden: Jwscf; doi: 10.1007/s10086-011-1189-7; Language of Original Document: English; Correspondence Address: Bai, S.-L.; Department of Advanced Materials and Nanotechnology, College of Engineering, Peking University, Beijing 100871, China; email: slbai@pku.edu.cn Approved no  
  Call Number EcoFoG @ webmaster @ Serial 363  
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Author Delabie, J.H.C.; Groc, S.; Dejean, A. url  openurl
  Title The tramp ant technomyrmex vitiensis (Hymenoptera: Formicidae: Dolichoderinae) on South America Type Journal Article
  Year (up) 2011 Publication Florida Entomologist Abbreviated Journal Fla. Entomol.  
  Volume 94 Issue 3 Pages 688-689  
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  Abstract Technomyrmex vitiensis is a tramp ant that has spread through many parts of the Old World tropics via human commerce. This species has been previously reported only once in the New World, from San Francisco, California. Here, we report the first records of T. vitiensis in South America, from two sites deep in the forest of French Guiana. It is not clear how these ants were transported to such remote sites, 100 km inland. Copyright © 2011 BioOne All rights reserved.  
  Address Université de Toulouse, UPS, 118 route de Narbonne, F-31062 Toulouse, France  
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  ISSN 00154040 (Issn) ISBN Medium  
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  Notes Export Date: 26 October 2011; Source: Scopus; Coden: Fetma; doi: 10.1653/024.094.0335; Language of Original Document: English; Correspondence Address: Delabie, J.H.C.; Universidade Estadual de Santa Cruz, Rodovia Ilhéus-Itabuna, Km 16, 45650-000 Ilhéus, Bahia, Brazil Approved no  
  Call Number EcoFoG @ webmaster @ Serial 364  
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Author Faucheux, M.J.; Gibernau, M. url  openurl
  Title Antennal sensilla in five Psychodini moth flies (Diptera: Psychodidae: Psychodinae) pollinators of Arum spp. (Araceae) Type Journal Article
  Year (up) 2011 Publication Annales de la Societe Entomologique de France Abbreviated Journal Ann. Soc. Entomol. Fr.  
  Volume 47 Issue 1-2 Pages 89-100  
  Keywords Chodopsycha; Deceptive pollination; Logima; Psycha; Psychoda  
  Abstract The pollination of the genus Arum (Araceae) is mainly achieved by deception, the floral odour mimicking the pollinator ovipositing site. In order to discover the sensory organs involved in this attraction, we have studied the antennae of five species of psychodine moth-flies (former Psychoda sensu lato = Psychodini), pollinators of Arum spp. The antennae of the five Psychodini reveal seven types of sensilla: multiporous tribranched sensilla basiconica (sensilla ascoidea), multiporous sensilla basiconica, multiporous sensilla coeloconica, multiporous sensilla auricillica, uniporous sensilla basiconica, aporous sensilla chaetica, aporous Böhm's sensilla. Each species possesses three, five or six of these sensillum types. All the multiporous sensilla are probably olfactory receptors while the uniporous sensilla basiconica must possess a contact chemoreceptive function. The multiporous tribranched sensilla basiconica (s. ascoidea), present in all the species, are the best candidates for the reception of the odours given off by the ovipositing sites and the inflorescences of Arum. The multiporous sensilla basiconica and the multiporous sensilla coeloconica may be involved respectively as CO2 receptors or thermoreceptors. Psychoda phalaenoides, which is the main pollinator of A. maculatum, is the species which possesses the largest number of antennal sensilla. The sexual dimorphism, studied only in Psycha grisescens, as concerns the number of sensilla and the absence of a sensillum type which differ according to sex, is difficult to interpret.  
  Address CNRS – Ecofog UMR 8172, BP 709, F-97387 Kourou, France  
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  ISSN 00379271 (Issn) ISBN Medium  
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  Notes Export Date: 26 October 2011; Source: Scopus; Language of Original Document: English; Correspondence Address: Faucheux, M.J.; Université de Nantes, Laboratoire d'Endocrinologie des Insectes Sociaux, 2 rue de la Houssinière, F-44322 Nantes Cedex 03, France; email: faucheux.michel@free.fr Approved no  
  Call Number EcoFoG @ webmaster @ Serial 365  
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