| |
Record |
Links |
|
Author  |
Conte, D.E.; Aboulaich, A.; Robert, F.; Olivier-Fourcade, J.; Jumas, J.C.; Jordy, C.; Willmann, P. |
|
| |
Title |
Sn-x[BPO4](1-x) composites as negative electrodes for lithium ion cells: Comparison with amorphous SnB0.6P0.4O2.9 and effect of composition |
Type |
Journal Article |
| |
Year |
2010 |
Publication |
Journal of Solid State Chemistry |
Abbreviated Journal |
J. Solid State Chem. |
|
| |
Volume |
183 |
Issue |
1 |
Pages |
65-75 |
|
| |
Keywords |
Sn-based composites; Lithium-ion batteries; Negative electrodes; Mossbauer spectroscopy; LixSn alloys |
|
| |
Abstract |
A comparative study of two Sn-based composite materials as negative electrode for Li-ion accumulators is presented. The former SnB0.6P0.4O2.9 obtained by in-situ dispersion of SnO in an oxide matrix is shown to be an amorphous tin composite oxide (ATCO). The latter Sn-0.72[BPO4](0.28) obtained by ex-situ dispersion of Sri in a borophosphate matrix consists of Sri particles embedded in a crystalline BPO4 matrix. The electrochemical responses of ATCO and Sn-0.72.[BPO4](0.28) composite in galvanostatic mode show reversible capacities of about 450 and 530 mAhg(-1), respectively, with different irreversible capacities (60% and 29%). Analysis of these composite materials by Sn-119 Mossbauer spectroscopy in transmission (TMS) and emission (CEMS) modes confirms that ATCO is an amorphous Sn-II composite oxide and shows that in the case of Sn-0.72[BPO4](0.28), the Surface of the tin clusters is mainly formed by Sn-II in an amorphous interface whereas the bulk of the clusters is mainly formed by Sn-0. The determination of the recoilless free fractions f (Lamb-Mossbauer factors) leads to the effective fraction of both Sn-0 and Sn-II species in such composites. The influence of chemical composition and especially of the surface-to-bulk tin species ratio oil the electrochemical behaviour has been analysed for several Sn-x[BPO4](1-x) composite materials (0.17 < x < 0.91). The cell using the compound Sn-0.72[BPO4](0.28) as active material exhibits interesting electrochemical performances (reversible capacity of 500 mAh g(-1) at C/5 rate). (C) 2009 Elsevier Inc. All rights reserved. |
|
| |
Address |
[Conte, Donato Ercole; Aboulaich, Abdelmaula; Robert, Florent; Olivier-Fourcade, Josette; Jumas, Jean-Claude] Univ Montpellier 2, CNRS, UMR 5253,Inst Charles Gerhardt, Equipe Agregats Interfaces & Mat Energie, F-34095 Montpellier, France, Email: iguanasornione@libero.it |
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
ACADEMIC PRESS INC ELSEVIER SCIENCE |
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0022-4596 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
ISI:000273834600010 |
Approved |
no |
|
| |
Call Number |
EcoFoG @ eric.marcon @ |
Serial |
83 |
|
| Permanent link to this record |
